Benzoyl chloride → HCID 70477659, 화합물

HRID 615309

반응식

HRID 615309 반응식
[Al+3].[Cl-].[Cl-].[Cl-].[C:5](Cl)(=[O:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[C:14]1([CH:20]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21]([OH:23])=[O:22])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(Cl)(Cl)(Cl)Cl>[C:5]([C:20]([C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21]([OH:23])=[O:22])(=[O:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

참가 물질

5

반응물 3

HCID 7412Benzoyl chlorideHCID 6451240Aluminum(III) ChlorideHCID 220152372-Phenyloctadecanoic acid

생성물 1

HCID 70477659HCID 70477659, 화합물수율 40.4%

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

To a one-liter glass reactor equipped with a mechanical stirrer, condenser, thermometer and addition funnel was charged 300 mls freshly distilled carbon tetrachloride. The flask and its contents were cooled to 0°-5° C. and 40 grams (0.30 mole) AlCl3 added slowly. This was followed by the dropwise addition of 42 grams (0.30 mole) benzoyl chloride and then 26.9 grams (0.075 mole) phenylstearic acid. The mixture was maintained at 0°-5° C. for one hour with agitation and then allowed to warm to room temperature and stirred overnight. A yield of 40.4 percent crude benzoylphenylstearic acid was obtained upon work up of the reaction mixture.

후처리

  1. customTo a one-liter glass reactor equipped with a mechanical stirrer, condenser
  2. additionthermometer and addition funnel
  3. temperatureThe flask and its contents were cooled to 0°-5° C.
  4. temperatureThe mixture was maintained at 0°-5° C. for one hour with agitation

출처 및 근거

ORD 기록
ord-a7c93e238e834ea980ec7e1b5bd81082
출처 데이터셋
uspto-grants-1985_02
특허 번호
US04499013

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