Ammonia → 1-Amino-5-nitroanthraquinone

HRID 616856

반응식

HRID 616856 반응식
N.[N+:2]([C:5]1[C:18]2[C:17](=[O:19])[C:16]3[C:11](=[C:12]([N+:20]([O-])=O)[CH:13]=[CH:14][CH:15]=3)[C:10](=[O:23])[C:9]=2[CH:8]=[CH:7][CH:6]=1)([O-:4])=[O:3].[Br-].[NH4+]>C(O)COCCO>[NH2:20][C:12]1[C:11]2[C:10](=[O:23])[C:9]3[C:18](=[C:5]([N+:2]([O-:4])=[O:3])[CH:6]=[CH:7][CH:8]=3)[C:17](=[O:19])[C:16]=2[CH:15]=[CH:14][CH:13]=1

참가 물질

5

반응물 3

HCID 222AmmoniaHCID 67059,10-Anthracenedione, 1,5-dinitro-HCID 25514Ammonium Bromide

생성물 1

HCID 2369001-Amino-5-nitroanthraquinone수율 86.2%

시약·촉매·용매 1

HCID 8117Diethylene Glycol용매

실험 절차

17.5 liters (STP)/hour of ammonia are passed, under normal pressure, for 40 minutes into a solution of 60 g of 1,5-dinitro-anthraquinone (97% pure) and 5 g of ammonium bromide in 450 g of diethylene glycol, at 220° C, while stirring vigorously. After cooling, the product is filtered off and washed with water. After drying, 46.5 g of 80.5% pure 1-amino-5-nitroanthraquinone (71.5% of theory) are obtained. The product contains 19.0% (19.0% of theory) of 1,5-diaminoanthraquinone.

후처리

  1. temperatureAfter cooling
  2. filtrationthe product is filtered off
  3. washwashed with water
  4. customAfter drying

출처 및 근거

ORD 기록
ord-42ecd82fc7ab4172b4756e4af9cb9977
출처 데이터셋
uspto-grants-1978_02
특허 번호
US04076736

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