1-Chloro-4-nitrobenzene → 1,3-Bis(4-nitrophenoxy)-2,2,4-trimethylpentane

HRID 620459

반응식

HRID 620459 반응식
[CH3:1][C:2]([CH3:10])([CH:5]([OH:9])[CH:6]([CH3:8])[CH3:7])[CH2:3][OH:4].[N+:11]([C:14]1[CH:19]=[CH:18][C:17](Cl)=[CH:16][CH:15]=1)([O-:13])=[O:12].[OH-:21].[Na+]>CS(C)=O>[N+:11]([C:14]1[CH:19]=[CH:18][C:17]([O:4][CH2:3][C:2]([CH3:10])([CH3:1])[CH:5]([O:9][C:17]2[CH:18]=[CH:19][C:14]([N+:11]([O-:12])=[O:21])=[CH:15][CH:16]=2)[CH:6]([CH3:8])[CH3:7])=[CH:16][CH:15]=1)([O-:13])=[O:12]

참가 물질

5

반응물 3

HCID 74741-Chloro-4-nitrobenzeneHCID 89462,2,4-Trimethyl-1,3-pentanediolHCID 14798Sodium Hydroxide

생성물 1

HCID 198606781,3-Bis(4-nitrophenoxy)-2,2,4-trimethylpentane

시약·촉매·용매 1

HCID 679Dimethyl Sulfoxide용매

실험 절차

146 g (1 mol) 2,2,4-trimethyl-1,3-dihydroxypentane, 346.5 g (2.2 mols) 4-nitrochlorobenzene and 140 g powdered sodium hydroxide were reacted using the same procedure described in Example 1 in 600 ml DMSO.

후처리

  1. customwere reacted

출처 및 근거

ORD 기록
ord-81048ea7faf3483092d2da47a242376d
출처 데이터셋
uspto-grants-1989_04
특허 번호
US04820866

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