Sulfamic Acid → HCID 178513042, 화합물

HRID 638022

반응식

HRID 638022 반응식
[C:1]([N:3]=[C:4]([NH2:6])[NH2:5])#[N:2].[NH2:7][S:8]([OH:11])(=[O:10])=[O:9]>O>[S:8](=[O:10])(=[O:9])([OH:11])[NH2:7].[C:4]([NH:3][C:1]([NH2:2])=[O:9])(=[NH:6])[NH2:5]

참가 물질

4

반응물 2

HCID 5987Sulfamic AcidHCID 10005Dicyandiamide

생성물 1

HCID 178513042HCID 178513042, 화합물수율 181.9%

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
95 °C

실험 절차

Dicyandiamide (84 g) was suspended in 80 ml of water and reacted successively with 97 g sulfaminic acid at 80° C. in such manner that the temperature of 95° C. was not exceeded. The reaction mixture was agitated for another 15 minutes at 95° C. Then the solution was rapidly cooled to 0° C.-5° C., and the resultant colorless crystals were drawn off and washed with 100 ml ethanol. After drying, 181 g (91%) guanylurea sulfamate was obtained.

후처리

  1. temperatureThen the solution was rapidly cooled to 0° C.-5° C.
  2. washwashed with 100 ml ethanol
  3. customAfter drying

출처 및 근거

ORD 기록
ord-8527a224217847a2962967f7ec5bf61e
출처 데이터셋
uspto-grants-1985_12
특허 번호
US04559409

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