Benzoyl chloride → Allyl benzoate

HRID 65133

반응식

HRID 65133 반응식
C(Cl)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10](=[O:19])([O:15][CH2:16][CH:17]=[CH2:18])OCC=C>[Cl-].[Zn+2].[Cl-]>[C:10]([O:15][CH2:16][CH:17]=[CH2:18])(=[O:19])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

4

반응물 2

HCID 7412Benzoyl chlorideHCID 84764Carbonic acid, di-2-propen-1-yl ester

생성물 1

HCID 11406Allyl benzoate수율 82%

시약·촉매·용매 1

HCID 3007855Zincchloride촉매

반응 조건

온도
60 °C

실험 절차

In a glass reactor benzoyl chloride (7.03 g, 0.05 mole), diallyl carbonate (7.1 g, 0.05 mole) and zinc chloride (0.136 g, 0.001 mole) were combined. The reacinitiated at room temperature. After heating at 60° C. for 3 hours and heating at 80° C. for an additional 3 hours, the reaction was discontinued. Distillation gave 6.65 g (78 percent yield) of allyl benzoate which was identified by nuclear magnetic resonance spectroscopy.

후처리

  1. customreacinitiated at room temperature
  2. temperatureheating at 80° C. for an additional 3 hours
  3. distillationDistillation

출처 및 근거

ORD 기록
ord-39ac0fe3490b4b4ca1802b534a76f6ac
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04612386

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