Benzoyl chloride → Allyl benzoate
반응식
C(Cl)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10](=[O:19])([O:15][CH2:16][CH:17]=[CH2:18])OCC=C>[Cl-].[Zn+2].[Cl-]>[C:10]([O:15][CH2:16][CH:17]=[CH2:18])(=[O:19])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1참가 물질
4
반응 조건
- 온도
- 60 °C
실험 절차
In a glass reactor benzoyl chloride (7.03 g, 0.05 mole), diallyl carbonate (7.1 g, 0.05 mole) and zinc chloride (0.136 g, 0.001 mole) were combined. The reacinitiated at room temperature. After heating at 60° C. for 3 hours and heating at 80° C. for an additional 3 hours, the reaction was discontinued. Distillation gave 6.65 g (78 percent yield) of allyl benzoate which was identified by nuclear magnetic resonance spectroscopy.
후처리
- customreacinitiated at room temperature
- temperatureheating at 80° C. for an additional 3 hours
- distillationDistillation
출처 및 근거
- ORD 기록
- ord-39ac0fe3490b4b4ca1802b534a76f6ac
- 출처 데이터셋
- uspto-grants-1986_09
- 특허 번호
- US04612386
반응 노트
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