Methyldichlorosilane → 3-Chloropropyldichloromethylsilane

HRID 65509

반응식

HRID 65509 반응식
[CH3:1][SiH:2]([Cl:4])[Cl:3].[SiH:5]([Cl:8])([CH3:7])[CH3:6].[CH2:9]([Cl:12])[CH:10]=[CH2:11]>>[CH3:1][Si:2]([CH2:11][CH2:10][CH2:9][Cl:12])([Cl:4])[Cl:3].[Si:5]([CH2:11][CH2:10][CH2:9][Cl:12])([CH3:7])([CH3:6])[Cl:8]

참가 물질

5

반응물 3

HCID 6376MethyldichlorosilaneHCID 7850Allyl chlorideHCID 66108Chlorodimethylsilane

생성물 2

HCID 822353-Chloropropyldichloromethylsilane수율 31.3%HCID 82765Silane, chloro(3-chloropropyl)dimethyl-수율 22.6%

반응 조건

온도
45 °C

실험 절차

In a 100 ml apparatus, there were combined 8.6 g (0.075 mol) of MeSiHCl2, 7.1 g (0.075 mol) of Me2SiHCl, and 5.7 g (0.075 mol) of allyl chloride. Pt catalyst solution (0.01 ml) was added at 37° C., followed by heating up to 45° C. over 1 hr. Vacuum distillation yielded 31.3% of MeSiCl2CH2CH2CH2Cl and 22.6% of Me2SiClCH2CH2CH2Cl. This example shows that neither Me2SiHCl nor MeSiHCl2 is a very effective promoter at the equimolar level for reactions of the other with allyl chloride.

후처리

  1. distillationVacuum distillation

출처 및 근거

ORD 기록
ord-446b3378e7ba490e872ef321e5d44e04
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04614812

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