1,3-Propanediamine → 4-Iodobiphenyl

HRID 722830

반응식

HRID 722830 반응식
Br[C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[I-:14].[Na+].C(N)CCN>C(O)CCCC>[I:14][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:4][CH:3]=1

참가 물질

5

반응물 3

HCID 4281,3-PropanediamineHCID 5238Sodium IodideHCID 71014-Bromobiphenyl2회

생성물 1

HCID 153224-Iodobiphenyl

시약·촉매·용매 1

HCID 62761-Pentanol용매

실험 절차

30 g of 4-bromobiphenyl is dissolved in 40 mL of n-pentanol. 2 equivalents of sodium iodide and 10 mole % of 1,3-propanediamine are added to the 4-bromobiphenyl solution. The reaction mixture is refluxed at 130° C. for sixteen (16) hours to produce 4-iodobiphenyl, as shown in reaction scheme (5).

출처 및 근거

ORD 기록
ord-e26975268c1443fcb894981069a57230
출처 데이터셋
uspto-grants-2006_11
특허 번호
US07138555B2

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