Triethylamine → 4-Imidazolidinone, 3-(diphenylmethyl)-1-methyl-2-thioxo-

HRID 742225

반응식

HRID 742225 반응식
[CH:1]([N:14]=[C:15]=[S:16])([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl.C([O:20][C:21](=O)[CH2:22][NH:23][CH3:24])C.C(N(CC)CC)C>C(Cl)(Cl)Cl>[CH:1]([N:14]1[C:21](=[O:20])[CH2:22][N:23]([CH3:24])[C:15]1=[S:16])([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

5

반응물 3

HCID 8471TriethylamineHCID 171173Ethyl N-methylaminoacetate hydrochlorideHCID 520742Benzhydryl isothiocyanate

생성물 1

HCID 111506254-Imidazolidinone, 3-(diphenylmethyl)-1-methyl-2-thioxo-

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

The title compound was prepared by the procedure described in Example 1 using 11.25 g of benzhydryl-isothiocyanate, 7.68 g of sarcosine ethyl ester hydrochloride, 12 g of triethyl amine, and 200 mL of chloroform. The title compound was obtained (7.40 g) as an off-white solid, m.p. 139°-141° C. Anal. Calcd. for C17H16N2O S: C, 68.89; H, 5.44; N, 9.45. Found: C, 68.92; H, 5.43; N, 9.58. Mass spectrum (El, M.+) m/z 296.

후처리

  1. customThe title compound was prepared by the procedure

출처 및 근거

ORD 기록
ord-bd0b8e661d7844e99bc0f045247d5240
출처 데이터셋
uspto-grants-1996_09
특허 번호
US05554607

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