Glycine → Bis-(2,2-dinitropropyl)-glycine

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[NH2:1][CH2:2][C:3]([OH:5])=[O:4].[OH-:6].[Na+].[N+:8]([C:11]([N+:15]([O-:17])=[O:16])([CH3:14])[CH2:12]O)([O-:10])=[O:9].S(=O)(=O)(O)O>O>[N+:8]([C:11]([N+:15]([O-:17])=[O:16])([CH3:14])[CH2:12][N:1]([CH2:12][C:11]([N+:8]([O-:10])=[O:9])([N+:15]([O-:16])=[O:6])[CH3:14])[CH2:2][C:3]([OH:5])=[O:4])([O-:10])=[O:9]

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실험 절차

A solution of 7.5 g. (0.1 mole) of glycine, 4.0 g. (0.1 mole) of sodium hydroxide and 50 ml. of water was mixed with 15.0 g. (0.1 mole) of 2,2-dinitropropanol. The temperature rose to 42° and the yellow solution formed was allowed to stand overnight. Upon addition of dilute sulfuric acid a viscous, colorless oil separated and solidified on standing. The product 15.6 g. (92.0%) was collected and recrystallized from methanol-water to give white crystals, m.p. 123°-124°.