Glycine → HCID 54517463, 화합물

HRID 745132

반응식

HRID 745132 반응식
[NH2:1][CH2:2][C:3]([OH:5])=[O:4].[OH-:6].[Na+].[N+:8]([C:11]([N+:15]([O-:17])=[O:16])([CH3:14])[CH2:12]O)([O-:10])=[O:9].S(=O)(=O)(O)O>O>[N+:8]([C:11]([N+:15]([O-:17])=[O:16])([CH3:14])[CH2:12][N:1]([CH2:12][C:11]([N+:8]([O-:10])=[O:9])([N+:15]([O-:16])=[O:6])[CH3:14])[CH2:2][C:3]([OH:5])=[O:4])([O-:10])=[O:9]

참가 물질

6

반응물 4

HCID 750GlycineHCID 1118Sulfuric AcidHCID 14798Sodium HydroxideHCID 701942,2-Dinitropropanol

생성물 1

HCID 54517463HCID 54517463, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A solution of 7.5 g. (0.1 mole) of glycine, 4.0 g. (0.1 mole) of sodium hydroxide and 50 ml. of water was mixed with 15.0 g. (0.1 mole) of 2,2-dinitropropanol. The temperature rose to 42° and the yellow solution formed was allowed to stand overnight. Upon addition of dilute sulfuric acid a viscous, colorless oil separated and solidified on standing. The product 15.6 g. (92.0%) was collected and recrystallized from methanol-water to give white crystals, m.p. 123°-124°.

후처리

  1. customrose to 42°
  2. customthe yellow solution formed
  3. customseparated
  4. custom(92.0%) was collected
  5. customrecrystallized from methanol-water
  6. customto give white crystals, m.p. 123°-124°

출처 및 근거

ORD 기록
ord-be0eb83bf49440fd8d006d9dff388a1c
출처 데이터셋
uspto-grants-1986_07
특허 번호
USH0000078

연결된 노트

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