Iodoethane → Ethyl(triphenylmethyl)amine

HRID 80320

반응식

HRID 80320 반응식
[C:1]1([C:7]([NH2:20])([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.I[CH2:22][CH3:23]>C(#N)C>[C:1]1([C:7]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)([C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)[NH:20][CH2:22][CH3:23])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

4

반응물 2

HCID 6340IodoethaneHCID 138598Tritylamine

생성물 1

HCID 4447360Ethyl(triphenylmethyl)amine수율 28%

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

Triphenylmethylamine (1.00 g, 3.86 mmol) (Wako Pure Chemical Industries, Ltd.) and iodoethane (1.50 g, 9.62 mmol) (Wako Pure Chemical Industries, Ltd.) were dissolved in acetonitrile (5 mL) (Wako Pure Chemical Industries, Ltd.), and the mixture was left to stand still at room temperature for 3 days. The solvent was distilled off under reduced pressure, and the residue was subjected to silica gel column chromatography (chloroform (Wako Pure Chemical Industries, Ltd.) as an eluent), to thereby obtain the title compound (0.31 g, 28% yield).

후처리

  1. waitthe mixture was left
  2. distillationThe solvent was distilled off under reduced pressure

출처 및 근거

ORD 기록
ord-b13daa3783284fc5acaee76552dcdb91
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08846012B2

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