Chlorotrimethylsilane → (Cyclohexyloxy)trimethylsilane

HRID 847481노트

반응식

HRID 847481 반응식
[CH:1]1([OH:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH3:8][Si:9]([CH3:12])([CH3:11])Cl>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC>[CH3:8][Si:9]([CH3:12])([CH3:11])[O:7][CH:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

참가 물질

4

반응물 2

HCID 6397ChlorotrimethylsilaneHCID 7966Cyclohexanol

생성물 1

HCID 262864(Cyclohexyloxy)trimethylsilane

시약·촉매·용매 1

HCID 74236Tetrabutylammonium Bromide촉매

실험 절차

1 mole of cyclohexanol, 1.5 moles of trimethylchorosilane and 0.0005 moles of tetra-n-butyl ammonium bromide were reacted at the reflux temperature (54°-97° C.) as in Example 1 and then worked up by distillation.

후처리

  1. distillationworked up by distillation

출처 및 근거

ORD 기록
ord-b2a40950a53b4bc1828648cbee2a62b4
출처 데이터셋
uspto-grants-1992_08
특허 번호
US05142081

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