p-Methoxybenzophenonoxime → 1-(4-Methoxyphenyl)-1-phenylmethanamine

HRID 862313

반응식

HRID 862313 반응식
[CH3:1][O:2][C:3]1[CH:17]=[CH:16][C:6]([C:7](=[N:14]O)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:5][CH:4]=1.C([O-])(=O)C.[NH4+].C([BH3-])#N.[Na+]>[Cl-].[Cl-].[Cl-].[Ti+3]>[CH3:1][O:2][C:3]1[CH:17]=[CH:16][C:6]([CH:7]([NH2:14])[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:5][CH:4]=1

참가 물질

5

반응물 3

HCID 185567p-MethoxybenzophenonoximeHCID 517165Ammonium AcetateHCID 5003444Sodium cyanoborohydride

생성물 1

HCID 3500411-(4-Methoxyphenyl)-1-phenylmethanamine수율 76.9%

시약·촉매·용매 1

HCID 10313229titanium(III) trichloride촉매

실험 절차

Following a procedure similar to that described in Preparation 12, but using 9.4 g of 4-methoxybenzophenone oxime, 33.9 g of ammonium acetate, 7.46 g of sodium cyanoborohydride, and 79 ml of a 17-19% by volume aqueous solution of titanium trichloride, 6.78 g of the title compound were obtained as an oily substance.

후처리

  1. customthat described in Preparation 12

출처 및 근거

ORD 기록
ord-4261112265e44ee085ca2bfb69a10958
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05717088

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