2,3-Dinitrophenol → Sodium dinitrophenolate

HRID 877866

반응식

HRID 877866 반응식
[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[H-].[Na+:15]>C(Cl)Cl.C1COCC1>[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([O-:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Na+:15]

참가 물질

5

반응물 2

HCID 61912,3-Dinitrophenol2회HCID 24758Sodium hydride2회

생성물 1

HCID 86649331Sodium dinitrophenolate

시약·촉매·용매 2

HCID 6344Dichloromethane용매HCID 8028Tetrahydrofuran용매

실험 절차

A commercially available dinitrophenol (10.0 g, 54.3 mmol) was dissolved in 250 mL of methylenechloride, and water was removed on anhydrous magnesium sulfate. Solvent was removed by filtration under the reduced pressure. After the anhydrous dinitrophenol (10.0 g, 54.3 mmol) was dissolved in anhydrous THF (300 mL), NaH (0.782 g, 32.6 mmol) was added slowly. After all NaH was added, the solution was stirred for 3 hrs. Solvent was removed under reduced pressure to obtain 60 mol % sodium dinitrophenolate.

후처리

  1. customwater was removed on anhydrous magnesium sulfate
  2. customSolvent was removed by filtration under the reduced pressure
  3. customSolvent was removed under reduced pressure

출처 및 근거

ORD 기록
ord-e9899c6861a0442297c0e52cecc1a07a
출처 데이터셋
uspto-grants-2015_03
특허 번호
US08987411B2

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