Acetic Acid → HCID 86650351, 화합물

HRID 885782노트

반응식

HRID 885782 반응식
Br[CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([F:9])([F:8])[F:7].[C:13]([O-:16])(=[O:15])[CH3:14].[K+].C(O)(=O)C>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC.C(#N)C>[C:13]([O:16][CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([F:9])([F:8])[F:7])(=[O:15])[CH3:14]

참가 물질

6

반응물 3

HCID 176Acetic AcidHCID 517044Potassium AcetateHCID 5153113CID 5153113

생성물 1

HCID 86650351HCID 86650351, 화합물

시약·촉매·용매 2

HCID 74236Tetrabutylammonium Bromide촉매HCID 6342Acetonitrile용매

실험 절차

24.8 g (0.1 mol) of 5-bromo-1,1,1-trifluoro-4-methoxypent-3-en-2-one, 20 g of potassium acetate, 5 g of tetrabutylammonium bromide and 8 g of acetic acid were stirred in 300 ml of acetonitrile at 40° C. for 20 h. The precipitate was filtered off and the solvent was removed completely under reduced pressure.

후처리

  1. filtrationThe precipitate was filtered off
  2. customthe solvent was removed completely under reduced pressure

출처 및 근거

ORD 기록
ord-7f330ea03c0e44b48d5c4db88bd3b0d1
출처 데이터셋
uspto-grants-2012_08
특허 번호
US08242313B2

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