1-Octanol → 1-(1-Octyloxy)ethyl acetate

HRID 916912

반응식

HRID 916912 반응식
C(=O)([O-])[O-].[Na+].[Na+].[CH2:7]([OH:15])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[C:16]([O:19][CH:20]=[CH2:21])(=[O:18])[CH3:17].C(OCCCCCCCC)=C.C(OCCCCCCCC)(=O)C>C1(C)C=CC=CC=1>[C:16]([O:19][CH:20]([O:15][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[CH3:21])(=[O:18])[CH3:17]

참가 물질

7

반응물 5

HCID 9571-OctanolHCID 7904Vinyl AcetateHCID 8164Octyl AcetateHCID 10340Sodium CarbonateHCID 702491-(Vinyloxy)octane

생성물 1

HCID 220345371-(1-Octyloxy)ethyl acetate

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
100 °C

실험 절차

To a mixture of di-1-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium carbonate (0.1 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (5 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether, octyl acetate, and 1-(1-octyloxy)ethyl acetate were produced in yields of 58%, 3%, and 21%, respectively, with a conversion from 1-octanol of 100%.

후처리

  1. additionwere added

출처 및 근거

ORD 기록
ord-9ae999423ea0441593e4508c7b2c6acf
출처 데이터셋
uspto-grants-2007_09
특허 번호
US07271297B2

연결된 노트

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