Benzene → Cyclohexyl acetate

HRID 926969

반응식

HRID 926969 반응식
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(O)CCCCC1.[C:14]([O:17]CC)(=[O:16])[CH3:15]>[Ru]>[C:14]([O:17][CH:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)(=[O:16])[CH3:15]

참가 물질

5

반응물 3

HCID 241BenzeneHCID 7966CyclohexanolHCID 8857Ethyl Acetate2회

생성물 1

HCID 12146Cyclohexyl acetate

시약·촉매·용매 1

HCID 23950Ruthenium촉매

실험 절차

When a benzene solution containing 15 mmols of cyclohexanol, 5 mmols of ethyl acetate and 0.05 mmols of complex 1 was refluxed under argon atmosphere, GC analysis after 28 hrs showed that all of the ethyl acetate disappeared and cyclohexyl acetate was formed as a single product (Table 8, entry 1). 1H NMR and GC-MS of the isolated product were identical to cyclohexyl acetate prepared by refluxing neat acetic anhydride with cyclohexanol.

후처리

  1. temperaturewas refluxed under argon atmosphere

출처 및 근거

ORD 기록
ord-94025d6f8b0e416db512913c31d4ab47
출처 데이터셋
uspto-grants-2016_03
특허 번호
US09290441B2

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