Azobisisobutyronitrile → 2-(Toluene-4-sulfonyloxy)ethyl methacrylate 3-hydroxypropyl methacrylate

HRID 968052

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HRID 968052 반응식
[C:1]([O:6][CH2:7][CH2:8][O:9][S:10]([C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][CH:14]=1)(=[O:12])=[O:11])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:20]([O:25][CH2:26][CH2:27][CH2:28][OH:29])(=[O:24])[C:21]([CH3:23])=[CH2:22].C(OC)(=O)C(C)=C.C(OCC1OC1)(=O)C(C)=C.CC(N=NC(C#N)(C)C)(C#N)C>O1CCCC1>[C:1]([O:6][CH2:7][CH2:8][O:9][S:10]([C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][CH:14]=1)(=[O:11])=[O:12])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:20]([O:25][CH2:26][CH2:27][CH2:28][OH:29])(=[O:24])[C:21]([CH3:23])=[CH2:22]

참가 물질

7

반응물 5

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 7837Glycidyl methacrylateHCID 176943-Hydroxypropyl methacrylateHCID 143442492-(Toluene-4-sulfonyloxy)ethyl methacrylate

생성물 1

HCID 867598762-(Toluene-4-sulfonyloxy)ethyl methacrylate 3-hydroxypropyl methacrylate수율 65%

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

반응 조건

온도
67.5 °C

실험 절차

In a 500 ml round-bottom flask was placed 0.3 mole of 2-(toluene-4-sulfonyloxy)ethyl methacrylate, 0.22 mole of 3-hydroxypropyl methacrylate, 0.15 mole of methyl methacrylate, 0.3 mole of glycidyl methacrylate, 300 g of tetrahydrofuran (THF), and 0.1 g-3 g of AIBN. The reaction mixture was heated at 60-75° C. for 5-20 hours. The product was precipitated in ethyl ether or n-hexane, filtered and dried to provide poly [2-(toluene-4-sulfonyloxy)ethyl methacrylate/3-hydroxypropyl methacrylate-/methyl methacrylate-/glycidyl methacrylate] represented by the following chemical formula 13, at a yield of 65-70%.

후처리

  1. customIn a 500 ml round-bottom flask was placed
  2. customThe product was precipitated in ethyl ether
  3. filtrationn-hexane, filtered
  4. customdried

출처 및 근거

ORD 기록
ord-a0c7d765352045bc8b57acd008bb8d34
출처 데이터셋
uspto-grants-2005_10
특허 번호
US06956091B2

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