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Copper(II) oxalate → Copper(II) oxalate

HRID 972464
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HRID 972464 반응식
[Mo:1](=O)(=O)=[O:2].C.C1(N)N=C(N)N=C(N)N=1.C1(N)N=C(N)N=C(N)N=1.[C:24]([O-:29])(=[O:28])[C:25]([O-:27])=[O:26].[Cu+2:30].C1C(=O)N(Br)C(=O)C1>>[Mo:1]=[O:2].[C:24]([O-:29])(=[O:28])[C:25]([O-:27])=[O:26].[Cu+2:30]
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참가 물질

6

반응물 4

HCID 13148Copper(II) oxalateHCID 14802Molybdenum trioxideHCID 67184N-bromobutanimideHCID 103335Molybdate (Mo2O72-), hydrogen, compd. with 1,3,5-triazine-2,4,6-triamine (1:2:1)

생성물 2

HCID 13148Copper(II) oxalateHCID 139765Molybdenum oxide

실험 절차

When molybdenum trioxide is substituted for the melamine molybdate in combination with the copper oxalate in the above compound, no practical synergism is noted with this combination. For example, in the flaming mode NBS smoke test Dm /g values of about 23 (58.8% smoke reduction relative to the standard compound of Example I) were obtained with ratios of 1.0 molybdenum oxide and 4.0 copper oxalate, 2.0 molybdenum oxide and 3.0 copper oxalate, 3.0 molybdenum oxide and 2.0 copper oxalate, 4.0 molybdenum oxide and 1.0 copper oxalate. In contrast, it should be noted that when 1.0 copper oxalate and 4.0 melamine molybdate were used in the same compound the Dm /g was 19.08 with a smoke reduction of 65.1%, and with 4.0 copper oxalate and 1.0 melamine molybdate the Dm /g was 19.92 and a 64.38% smoke reduction.

출처 및 근거

ORD 기록
ord-eed27a03226344f3961a5d7f29d55a3b
출처 데이터셋
uspto-grants-1977_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04053453

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