2,4-Dinitrophenol → HCID 54299897, compound

HRID 1003714Notes

Reaction equation

HRID 1003714 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1O)([O-:3])=[O:2].[C:14]([O-:17])([O-])=O.[K+].[K+].ICCCCC[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37]C>CC(N(C)C)=O>[N+:10]([CH:8]([CH2:9][CH:4]([N+:1]([O-:3])=[O:2])[CH2:5][CH2:6][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH3:26])[CH2:7][O:17][C:14]1[CH:8]=[CH:9][CH:4]=[CH:5][CH:6]=1)([O-:12])=[O:11]

Participants

5

Reactant 3

HCID 14932,4-DinitrophenolHCID 11430Potassium CarbonateHCID 124021-Iodooctadecane

Product 1

HCID 54299897HCID 54299897, compoundYield 72%

Reagents, catalysts & solvents 1

HCID 31374DimethylacetamideSolvent

Procedure

To a 250 ml reactor equipped with an agitator and nitrogen-inlet, nitrogen gas was slowly influxed as 2,4-dinitrophenol (7.36 g, 0.04 mole) was dissolved in 50 ml of the reacting solvent of dimethylacetamide. While influxing nitrogen gas, K2CO3 (6.99 g, 0.05 mole), 1-iodooctadecane (19 g, 0.05 mole) was slowly added and refluxed for 48 hours. The mixture was precipitated in excess distilled water. Thereafter, the solid material so filtered was recrystalized to obtain 2,4-dinitro-octadecanoxy-benzene (DN-L-18O) with the yield of 72%.

Workup

  1. customTo a 250 ml reactor equipped with an agitator and nitrogen-inlet, nitrogen gas
  2. additionwas slowly added
  3. temperaturerefluxed for 48 hours
  4. customThe mixture was precipitated
  5. distillationin excess distilled water
  6. filtrationThereafter, the solid material so filtered
  7. customwas recrystalized

Sources & evidence

ORD record
ord-b0e6362a8ce042fc8a04ea85285a252f
Source dataset
uspto-grants-2000_04
Patent number
US06046303

Reaction notes

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