Tetrabutylammonium Fluoride → HCID 18790896, compound

HRID 1005262Notes

Reaction equation

HRID 1005262 reaction equation
[Si]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([CH2:17][CH2:18][CH2:19][CH3:20])[CH:15]=[CH2:16])(C(C)(C)C)(C)C.[F-].C([N+](CCCC)(CCCC)CCCC)CCC>C1COCC1>[CH2:17]([CH:14]([CH:15]=[CH2:16])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][OH:8])[CH2:18][CH2:19][CH3:20]

Participants

4

Reactant 2

HCID 2724141Tetrabutylammonium FluorideHCID 18790897HCID 18790897, compound

Product 1

HCID 18790896HCID 18790896, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

8-(tert-butyldimethylsilyloxy)-3-butyloct-1-ene (4.0 g, 13.4 mmol) was added to a solution of tetrabutylammonium fluoride (1 M, 14 ml) in THF, and the mixture was stirred at ambient temperature for 24 h. Standard work-up followed by PMPLC yielded 2.05 g (83%) of 6-butyl-7-en-1-ol.

Workup

  1. customyielded 2.05 g (83%) of 6-butyl-7-en-1-ol

Sources & evidence

ORD record
ord-e0dbc86556564279a5ad31c3be09c44a
Source dataset
uspto-grants-2000_04
Patent number
US06054141

Reaction notes

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