Tetrahydrofuran → HCID 178479811, compound

HRID 1006571Notes

Reaction equation

HRID 1006571 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][N:3]=1.[CH2:8]([N:10](CC)CC)C.[Pt:15]([Cl:19])(Cl)(Cl)[Cl:16].[CH2:20]1[CH2:24][O:23][CH2:22][CH2:21]1>>[N:3]1[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=1[O:1][Pt:15]([Cl:19])([Cl:16])[O:23][C:24]1[CH:20]=[CH:21][CH:22]=[CH:8][N:10]=1

Participants

5

Reactant 4

HCID 8028TetrahydrofuranHCID 8471TriethylamineHCID 26031Platinum tetrachlorideHCID 178516071HCID 178516071, compound

Product 1

HCID 178479811HCID 178479811, compound

Procedure

To a solution of 0.02 moles of 2-hydroxypyridine and 0.02 moles of triethylamine in 50 mL of THF, a solution of 0.01 moles of platinum tetrachloride is added dropwise at 0° C. The solution is then stirred overnight at room temperature. After filtration, the THF solution is evaporated and the product is extracted from the residue. Polymers may be produced using the catalyst by following the procedure of Example 4.

Workup

  1. filtrationAfter filtration
  2. customthe THF solution is evaporated
  3. extractionthe product is extracted from the residue
  4. customPolymers may be produced

Sources & evidence

ORD record
ord-e01dcbfbc80047c28c6db724fdeb6397
Source dataset
uspto-grants-2004_09
Patent number
US06790918B2

Reaction notes

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