Tributylstannane → HCID 22670687, compound

HRID 1007662Notes

Reaction equation

HRID 1007662 reaction equation
[C:1]([O:9][CH:10]([CH2:13][S:14]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1Br)(=[O:16])=[O:15])[CH:11]=[CH2:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([SnH](CCCC)CCCC)CCC.CC(N=NC(C#N)(C)C)(C#N)C>>[C:1]([O:9][CH:10]1[CH2:11][CH2:12][C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][C:17]=2[S:14](=[O:16])(=[O:15])[CH2:13]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 5948TributylstannaneHCID 6547AzobisisobutyronitrileHCID 22670695HCID 22670695, compound

Product 1

HCID 22670687HCID 22670687, compound

Procedure

In Synlett, 9, 943-944(1995) 2-bromophenyl 3-benzoyloxy-1-buten-4-yl sulfone was treated with tributyl tin hydride and AIBN to produce 3-benzoyloxytetrahydrobenzothiepine-1,1-dioxide.

Sources & evidence

ORD record
ord-e977f0806d0043879ab987f831717b2e
Source dataset
uspto-grants-2004_09
Patent number
US06794544B2

Reaction notes

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