HRID1019234

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5360545

Sodium

HCID10488827

未命名化合物

HCID22603806

未命名化合物

PRODUCTS

生成物

$结构：COc1cc(OC)c(C(/C=C\c2ccc(OC(C)=O)c(OC)c2)SC(/C=C\c2ccc(OC(C)=O)c(OC)c2)c2cc(OC)c(OC)cc2OC)cc1OC$

HCID86585665

未命名化合物

PROCEDURE

实验过程

A solution of 3-methoxy-4-acetoxyphenylacetylene (0.02 mol), 2,4,5-trimethoxybenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) is subjected to General Procedure 2 to form (Z)-3-methoxy-4-acetoxystyryl-2,4,5-trimethoxybenzylsulfide. The title compound is obtained following oxidation of the sulfide, according to General Procedure 2.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7ecf269cd7b049f6ae3063e401fa8a19
来源数据集: uspto-grants-2002_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06486210B2
来源说明: uspto-grants-2002_11

反应 SMILES

[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:13]#[CH:14])[CH:6]=[CH:7][C:8]=1[O:9][C:10](=[O:12])[CH3:11].[CH3:15][O:16][C:17]1[CH:24]=[C:23]([O:25][CH3:26])[C:22]([O:27][CH3:28])=[CH:21][C:18]=1[CH2:19][SH:20].[Na]>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:6]=[CH:7][C:8]=1[O:9][C:10](=[O:12])[CH3:11])/[CH:13]=[CH:14]\[CH:19]([S:20][CH:19](/[CH:14]=[CH:13]\[C:5]1[CH:6]=[CH:7][C:8]([O:9][C:10](=[O:12])[CH3:11])=[C:3]([O:2][CH3:1])[CH:4]=1)[C:18]1[CH:21]=[C:22]([O:27][CH3:28])[C:23]([O:25][CH3:26])=[CH:24][C:17]=1[O:16][CH3:15])[C:18]1[CH:21]=[C:22]([O:27][CH3:28])[C:23]([O:25][CH3:26])=[CH:24][C:17]=1[O:16][CH3:15]