m-Chloroperbenzoic acid → HCID 131723658, compound

HRID 1019240Notes

Reaction equation

HRID 1019240 reaction equation
[CH3:1][C:2]12[CH2:11][CH2:10][C@@H:9]([C:12]([CH3:14])=[CH2:13])[CH2:8][C:7]1=[C:6]([CH2:15][CH2:16][CH3:17])[C:5](=[O:18])[CH2:4][CH2:3]2.ClC1C=CC=C(C(OO)=[O:27])C=1>C(Cl)Cl>[CH3:1][C:2]12[CH2:11][CH2:10][C@@H:9]([C:12]3([CH3:14])[O:27][CH2:13]3)[CH2:8][C:7]1=[C:6]([CH2:15][CH2:16][CH3:17])[C:5](=[O:18])[CH2:4][CH2:3]2

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 131723659HCID 131723659, compound

Product 1

HCID 131723658HCID 131723658, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

A mixture of 1.68 g (6.83 mmol) of compound obtained from step A, 1.24 g (7.17 mmol) of m-chloroperbenzoic acid was dissolved in 100 mL of methylene chloride and stirred at room temperature for 4 hours. After 4 filtration, the filtrate was washed with 10 mL of 1 N NaOH solution, brine, dried and evaporated to give title product.

Workup

  1. filtrationAfter 4 filtration
  2. washthe filtrate was washed with 10 mL of 1 N NaOH solution, brine
  3. customdried
  4. customevaporated

Sources & evidence

ORD record
ord-352c4ec2dda9475599fd21309aaceb8a
Source dataset
uspto-grants-2002_11
Patent number
US06486201B1

Reaction notes

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