trans-Stilbene → Stilbene

HRID 1022364Notes

Reaction equation

HRID 1022364 reaction equation
[C:1]1(/[CH:7]=[CH:8]/[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>CO>[C:1]1([CH:7]=[CH:8][C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 1

HCID 638088trans-Stilbene

Product 1

HCID 11502Stilbene

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

Into a 30 mL two-neck flask, a methanol solution (0.04 g/L, 70 μL) of the [HPS-N(C2H4OC2H4OCH3)3Br]Pt particle complex prepared in Example 17 and 180 mg of trans-stilbene were charged and thereto, 2 mL of methanol was added. The inside of the system was purged with hydrogen and the reaction was effected at room temperature for 11 hours. A dibenzyl derived from reduction of trans-stilbene was obtained in a yield measured by G.C. of 93%.

Workup

  1. customThe inside of the system was purged with hydrogen
  2. customwas obtained in a yield

Sources & evidence

ORD record
ord-9d925e81eb1d401ca6042cdccf707c34
Source dataset
uspto-grants-2014_05
Patent number
US08722562B2

Reaction notes

Loading…