Hydrogen Peroxide → HCID 15752803, compound

HRID 1030329Notes

Reaction equation

HRID 1030329 reaction equation
[S:1]([C:16]1[CH:21]=[C:20]([CH:22]2[CH2:27][CH2:26][CH2:25][CH2:24][CH2:23]2)[C:19]([OH:28])=[CH:18][C:17]=1[CH3:29])[C:2]1[CH:7]=[C:6]([CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[C:5]([OH:14])=[CH:4][C:3]=1[CH3:15].[OH:30]O>CO>[S:1]([C:16]1[CH:21]=[C:20]([CH:22]2[CH2:27][CH2:26][CH2:25][CH2:24][CH2:23]2)[C:19]([OH:28])=[CH:18][C:17]=1[CH3:29])([C:2]1[CH:7]=[C:6]([CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[C:5]([OH:14])=[CH:4][C:3]=1[CH3:15])=[O:30]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 15752802HCID 15752802, compound

Product 1

HCID 15752803HCID 15752803, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a solution of crude oily 4,4'-thiobis(6-cyclohexyl-3-methylphenol) (10.5 g) in methanol (40 ml) is gradually added dropwise 30% hydrogen peroxide (6.5 g) at room temperature. The mixture is stirred for a while at the same temperature, and left standing at 50° C. for 3 hours and overnight at room temperature. The precipitated crystals are filtered off, washed with cool methanol and dried to give 4,4'-sulfinylbis(6-cyclohexyl-3-methylphenol), m.p. 151°-153° C.

Workup

  1. waitleft
  2. filtrationThe precipitated crystals are filtered off
  3. washwashed with cool methanol
  4. customdried

Sources & evidence

ORD record
ord-8577f808617545149435a6adff16499b
Source dataset
uspto-grants-1992_04
Patent number
US05105016

Reaction notes

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