Butyl bromide → HCID 18958204, compound
Reaction equation
[C:1]1([CH3:22])[CH:6]=[CH:5][C:4]([P:7]([C:15]2[CH:20]=[CH:19][C:18]([CH3:21])=[CH:17][CH:16]=2)[C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.[Br:23][CH2:24][CH2:25][CH2:26][CH3:27]>C1(C)C(C)=CC=CC=1>[Br-:23].[CH2:24]([P+:7]([C:4]1[CH:5]=[CH:6][C:1]([CH3:22])=[CH:2][CH:3]=1)([C:15]1[CH:16]=[CH:17][C:18]([CH3:21])=[CH:19][CH:20]=1)[C:8]1[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=1)[CH2:25][CH2:26][CH3:27]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 45 °C
Procedure
Into a 50 milliliter glass reactor equipped with a thermometer connected to a temperature controller, a heating mantle, a condenser and a magnetic stirring bar, is charged 5 gms (0.0164 mole) of tri-p-tolyl phosphine and 24 gms of xylene. The slurry is heated to 45° C. then 2.7 gms (0.0197 mole) of 1-bromo butane is added. This reaction mass is heated to 50° C. and maintained at that temperature for 0.65 hour, then heated to 80 C. and maintained at that temperature for 16.08 hours, then heated to 100 C. and maintained at that temperature for -0.97 hour. The salt is decanted and then vacuum dried. There is obtained 2.098 gms of an oily catalyst.
Workup
- customInto a 50 milliliter glass reactor equipped with a thermometer
- temperatureThis reaction mass is heated to 50° C.
- temperaturemaintained at that temperature for 0.65 hour
- temperatureheated to 80 C
- temperatureand maintained at that temperature for 16.08 hours
- temperatureheated to 100 C
- temperatureand maintained at that temperature for -0.97 hour
- customThe salt is decanted
- customvacuum dried
- customThere is obtained 2.098 gms of an oily catalyst
Sources & evidence
- ORD record
- ord-602bfebccb384c20b8d4ded4e1552e2d
- Source dataset
- uspto-grants-1994_05
- Patent number
- US05310853
Reaction notes
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