Triethylamine → 2-Methyladamantan-2-yl Acrylate (stabilized with MEHQ)

HRID 1063091Notes

Reaction equation

HRID 1063091 reaction equation
[CH3:1][C:2]1([OH:12])[CH:9]2[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:11][CH:3]1[CH2:4]3)[CH2:8]2.C(N(CC)CC)C.[C:20](Cl)(=[O:23])[CH:21]=[CH2:22]>C1COCC1>[C:20]([O:12][C:2]1([CH3:1])[CH:3]2[CH2:11][CH:7]3[CH2:6][CH:5]([CH2:10][CH:9]1[CH2:8]3)[CH2:4]2)(=[O:23])[CH:21]=[CH2:22]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 13140Acryloyl chlorideHCID 1365452-Methyl-2-adamantanol

Product 1

HCID 112182922-Methyladamantan-2-yl Acrylate (stabilized with MEHQ)

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

17 g (0.1 mol) of 2-methyl-2-adamantanol and 11 g (0.11 mol) of triethylamine were dissolved in 250 ml of anhydrous THF and 10 g (0.11 mol) of acryloyl chloride was slowly added thereto at room temperature, and then the reactant was reacted for about 12 hours.

Workup

  1. customat room temperature, and then the reactant was reacted for about 12 hours

Sources & evidence

ORD record
ord-fba23771fa4544eb87870d2dc38fb1a8
Source dataset
uspto-grants-2005_11
Patent number
US06964839B1

Reaction notes

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