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HRID1066546

反应详情

EQUATION

反应方程式

HRID 1066546 的结构方程式

REACTANTS

反应物

5
结构：CCOC(=O)c1ccc(O)cc1
HCID8434

未命名化合物

结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：CC[C@H](C)CO
HCID2723602

(-)-2-Methyl-1-butanol

C5H12O

结构：CCOC(=O)/N=N/C(=O)OCC
HCID5462977

(E)-Diethyl azodicarboxylate

C6H10N2O4

结构：CCCCCCCCOC(=O)c1ccc(-c2ccc(OC(=O)OC)cc2)cc1
HCID18328376

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)c1ccc(OC[C@@H](C)CC)cc1
HCID53733015

未命名化合物

PROCEDURE

实验过程

Quantities: (S)-(-)-2-methylbutan-1-ol (5.00 g, 0.057 mol), ethyl 4-hydroxybenzoate (7) (9.47 g, 0.057 mol), DEAD (9.93 g, 0.057 mol), triphenylphosphine (14.95 g, 0.057 mol). The experimental preocedure was as described for the preparation of compound 5. The crude product was purified by column chromatography (10% petrol/dichloromethane) to give a colourless oil.

WORKUP

后处理

  1. customThe crude product was purified by column chromatography (10% petrol/dichloromethane)
  2. customto give a colourless oil