Methanol → HCID 178496795, compound

HRID 1067919Notes

Reaction equation

HRID 1067919 reaction equation
CO[C:3](OC)=[N:4][NH:5][C:6]([O:8][CH3:9])=[O:7].[CH3:12][NH2:13].[CH3:14][OH:15]>>[CH3:14][O:15][CH2:12][NH:13][CH:3]=[N:4][NH:5][C:6]([O:8][CH3:9])=[O:7]

Participants

4

Reactant 3

HCID 887MethanolHCID 6329MethylamineHCID 10986557HCID 10986557, compound

Product 1

HCID 178496795HCID 178496795, compoundYield 76%

Procedure

0.95 g (5.00 mmol) of methyl N′-dimethoxymethylenehydrazinecarboxylate (85% pure) was admixed with 3.57 g of a 44% strength solution of methylamine (50 mmol) in methanol, and the mixture was stirred at room temperature for 3 days. Work-up and removal of the solvent gave 0.85 g (76%) of methyl N′-(methoxymethylaminomethylene)hydrazinecarboxylate in the form of an oil.

Workup

  1. customWork-up and removal of the solvent

Sources & evidence

ORD record
ord-29181a5fc9604c60b34cfef33fb155b1
Source dataset
uspto-grants-2001_06
Patent number
US06248900B1

Reaction notes

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