Triphenylphosphine → Silane, trichloro[(trimethylsilyl)methyl]-

HRID 1068514Notes

Reaction equation

HRID 1068514 reaction equation
C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.Cl[CH2:21][Si:22]([CH3:25])([CH3:24])[CH3:23].[Cl:26][SiH:27]([Cl:29])[Cl:28]>>[Cl:26][Si:27]([Cl:29])([Cl:28])[CH2:21][Si:22]([CH3:25])([CH3:24])[CH3:23].[Cl:26][SiH:27]([Cl:28])[CH2:21][Si:22]([CH3:25])([CH3:24])[CH3:23]

Participants

5

Reactant 3

HCID 11776TriphenylphosphineHCID 24811TrichlorosilaneHCID 75361Silane, (chloromethyl)trimethyl-

Product 2

HCID 11816894Silane, trichloro[(trimethylsilyl)methyl]-Yield 70%HCID 57370759HCID 57370759, compoundYield 7%

Procedure

In the same apparatus and procedure as Example 1 above, 0.20 g (0.75 mmol) of triphenylphosphine, 1.38 g (7.5 mmol) of (chloromethyl)trimethylsilane, and 5.08 g (37.5 mmol) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.2 g of 1,1,1,-trichloro-3,3-dimethyl-1,3-disilabutane (bp; 173-174° C., yield; 70%) and 0.1 g of 1,1-dichloro-3,3-dimethyl-1,3-disilabutane (bp; 157-159° C., yield; 7%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-e4864bfb00c945da96b981a3089537cc
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Reaction notes

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