Triethylamine → HCID 11447904, compound

HRID 1068525Notes

Reaction equation

HRID 1068525 reaction equation
C(N(CC)CC)C.[F:8][C:9]1[CH:16]=[CH:15][C:12]([CH2:13]Cl)=[CH:11][CH:10]=1.[Cl:17][SiH:18]([Cl:20])[Cl:19]>>[F:8][C:9]1[CH:16]=[CH:15][C:12]([CH2:13][Si:18]([Cl:20])([Cl:19])[Cl:17])=[CH:11][CH:10]=1

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 96024-Fluorobenzyl chlorideHCID 24811Trichlorosilane

Product 1

HCID 11447904HCID 11447904, compoundYield 24.6%

Procedure

In the same apparatus and procedure as Example 1 above, 0.044 g (0.40 mmol) of triethylamine, 0.60 g (4.0 mmol) of 4-fluorobenzyl chloride, and 2.71 g (20.0 mmol) of trichlorosilane were reacted at 150° C. for 40 hrs. The resulting mixture was distilled to give 0.24 g of (4-fluorobenzyl)trichlorosilane (yield; 24%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-1f91b3f43cdb4901bc61cf6659568b95
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Reaction notes

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