Hydrochloric Acid → 1-Hexene

HRID 1072775Notes

Reaction equation

HRID 1072775 reaction equation
C(Cl)(C)(C)C.Cl.ClC(C)C.Cl[SiH](Cl)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Cl:20][Si:21]([Cl:29])([Cl:28])CCCCCC.ClCCCCCC>>[CH2:13]=[CH:14][CH2:15][CH2:16][CH2:17][CH3:18].[Cl:20][SiH:21]([Cl:29])[Cl:28]

Participants

8

Reactant 6

HCID 313Hydrochloric AcidHCID 63612-ChloropropaneHCID 10486tert-BUTYL CHLORIDE2×HCID 109921-ChlorohexaneHCID 13571HexyltrichlorosilaneHCID 92038703Dichloro(hexyl)silane

Product 2

HCID 115971-HexeneYield 17.9%HCID 24811Trichlorosilane

Procedure

The present experiement was described as shown in the following typical experimental No. 63 in Table 13. The reaction was carried out under the same condition as in Example 3, except that the same amount of t-butyl chloride was, used as the hydrogen chloride source. A mixture of 2-chloropropane and t-butyl chloride having the mixing ratio of 1:6 was reacted with metallic silicon at 280° C. to give 16.1 g of reaction products. The reaction products contained 5.9 g (45.2%) of 1,1-dichloro-1-silaheptane and 1.4 g (9.0%) of 1,1,1-trichloro-1-silaheptane. As other by-products, 31.1 g (13.2%) of 1-chlorohexane which is remained unreacted, 1.1 g (17.9%) of hexene, 2.5 g of trichlorosilane, and unconfirmed materials were obtained.

Workup

  1. customwas reacted with metallic silicon at 280° C.
  2. customto give
  3. custom16.1 g of reaction products

Sources & evidence

ORD record
ord-3a7588af8733467eadf3b8d95251708d
Source dataset
uspto-grants-2005_06
Patent number
US06911552B2

Reaction notes

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