Hydrogen Peroxide → Bis(perfluoroalkanoyl)peroxide
Reaction equation
[OH:1][OH:2].[F:3][C:4]([F:9])([F:8])[C:5]([OH:7])=O>O>[F:3][C:4]([F:9])([F:8])[C:5]([O:1][O:2][C:5](=[O:7])[C:4]([F:9])([F:8])[F:3])=[O:7]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
It is possible to use a lower concentration of hydrogen peroxide. For example, from a commercially available 30% solution of hydrogen peroxide in water it is possible to produce an 8% (mole) solution of bis(trifluoroacetyl) peroxide (BPFAP) in trifluoroacetic acid. This solution was obtained when 30% H2O2 (1.77 g, 15.6 mmol H2O2) was added dropwise into a well-stirred solution of RfCOOK (6.8 mg, 0.047 mmol) in freshly distilled bis(trifluoroacetyl) anhydride (21 g, 100 mmol) at 0° C. After adding the H2O2, the reaction mixture was stirred for 10 minutes (min) at 0° C. The concentration of BPFAP was measured by 19F NMR spectra.
Sources & evidence
- ORD record
- ord-faf1d0996f9949b982a4c3a6a1438aaa
- Source dataset
- uspto-grants-2005_06
- Patent number
- US06911561B2
Reaction notes
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