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HRID1073464

反应详情

EQUATION

反应方程式

HRID 1073464 的结构方程式

REACTANTS

反应物

1
结构：O=C(O)C(F)(F)C1(O)O[C@H](COCc2ccccc2)[C@@H](OCc2ccccc2)[C@@H]1OCc1ccccc1
HCID131716690

未命名化合物

PRODUCTS

生成物

1
结构：OC1(C(F)F)O[C@H](COCc2ccccc2)[C@@H](OCc2ccccc2)[C@@H]1OCc1ccccc1
HCID70360435

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1cccc(C)n1
溶剂HCID7937

2,6-Dimethylpyridine

C7H9N

PROCEDURE

实验过程

A stirred solution of 2.57 g of 2-deoxy-2,2-difluoro-4,5,7-tris-O-(phenylmethyl)-D-arabino-3-heptulofuranosonic acid in 25 ml of 2,6-lutidine was refluxed for 2 hours and then concentrated. The residue was subjected to column chromatography on silica gel to give an oil, CMR δ 113.1 (triplet, J=247Hz, CF2).

WORKUP

后处理

  1. concentrationconcentrated
  2. customto give an oil, CMR δ 113.1 (triplet, J=247Hz, CF2)