Diethyl Ether → HCID 21489638, compound

HRID 1076759Notes

Reaction equation

HRID 1076759 reaction equation
[CH2:1]([S:13][CH2:14][CH2:15][OH:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].CCOCC.[CH:22]1([C:25](Cl)=[O:26])[CH2:24][CH2:23]1>N1C=CC=CC=1>[CH:22]1([C:25]([O:16][CH2:15][CH2:14][S:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])=[O:26])[CH2:24][CH2:23]1

Participants

5

Reactant 3

HCID 3283Diethyl EtherHCID 73835Ethanol, 2-(dodecylthio)-HCID 77637Cyclopropanecarbonyl chloride

Product 1

HCID 21489638HCID 21489638, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a mixture of 2.0 g. 2-hydroxyethyl dodecyl sulfide, 60 ml. anhydrous ether and 1.27 g. cyclopropyl carboxylic acid chloride at 0° is added 1.3 ml. pyridine. The mixture is allowed to warm to room temperature and is stirred for three days. The product is isolated using the procedure of Example 3 to yield 3-thiapentadecyl cyclopropanecarboxylate, boiling point 131°-137° (0.03 mm.).

Workup

  1. additionTo a mixture of 2.0 g
  2. customThe product is isolated

Sources & evidence

ORD record
ord-370644912f2b4b8d97f756b00b6f8e1b
Source dataset
uspto-grants-1976_05
Patent number
US03957849

Reaction notes

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