HCID 22134093, compound → HCID 19428705, compound

HRID 1079101Notes

Reaction equation

HRID 1079101 reaction equation
[P:1]([O-:20])([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[C:21]([O-:25])(C)([CH3:23])[CH3:22].[Na+].[CH2:27]([CH2:39][C:40](=[S:42])C)[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36]CC>COC(C)(C)C>[CH2:40]([S:42][CH2:22][C:21]([OH:25])([CH3:23])[P:1]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])(=[O:20])[O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH2:39][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36]

Participants

5

Reactant 3

HCID 22134093HCID 22134093, compoundHCID 22146052HCID 22146052, compoundHCID 23676156Sodium t-butoxide

Product 1

HCID 19428705HCID 19428705, compound

Reagents, catalysts & solvents 1

HCID 15413tert-Butyl methyl etherSolvent

Procedure

25.6 g (83.6 mmol) of dioctyl phosphite are initially introduced into 100 ml of tert-butyl methyl ether, 0.4 g of sodium tert-butanolate are added, and 20.0 g (77.4 mmol) of dodecylthioacetone are subsequently introduced.

Workup

  1. additionare added

Sources & evidence

ORD record
ord-64a8dc95002445a7a51ac310797f2802
Source dataset
uspto-grants-1996_08
Patent number
US05550276

Reaction notes

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