4-Chloro-1,2-dinitrobenzene → HCID 22922483, compound

HRID 1081466Notes

Reaction equation

HRID 1081466 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[C:4]([N+:11]([O-])=O)[CH:3]=1.[C:14](N)([CH2:17][C:18]([CH3:21])([CH3:20])[CH3:19])([CH3:16])[CH3:15]>CCO>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[C:4]([NH:11][C:14]([CH3:16])([CH3:15])[CH2:17][C:18]([CH3:21])([CH3:20])[CH3:19])[CH:3]=1

Participants

4

Reactant 2

HCID 330974-Chloro-1,2-dinitrobenzeneHCID 61017tert-Octylamine

Product 1

HCID 22922483HCID 22922483, compoundYield 46.2%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 20 g of 4-chloro-1,2-dinitrobenzene and 30 g of tert-octylamine in 300 ml of 95° EtOH is refluxed for 16 hours. The solvent is evaporated off under vacuum to give 13 g of the expected product after crystallization from an iso ether/heptane mixture (40/60; v/v). M.p.=108° C.

Workup

  1. temperatureis refluxed for 16 hours
  2. customThe solvent is evaporated off under vacuum

Sources & evidence

ORD record
ord-aa8b20be75e44803abd43febbb018557
Source dataset
uspto-grants-1996_12
Patent number
US05585394

Reaction notes

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