Methacrylic Acid → HCID 86588650, compound

HRID 1085396Notes

Reaction equation

HRID 1085396 reaction equation
[C:1]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:10]([OH:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N>ClCCCl>[C:1]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:10]([OH:15])(=[O:14])[C:11]([CH3:13])=[CH2:12]

Participants

5

Reactant 3

HCID 4093Methacrylic AcidHCID 7274Allyl methacrylateHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)

Product 1

HCID 86588650HCID 86588650, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

To a solution of 113.4 g of allyl methacrylate and 8.6 g of methacrylic acid dissolved in 2 liters of 1,2-dichloroethane was added 1.8 g of 2,2'-azobis(2,4-dimethylvaleronitrile) as the polymerization initiator and the mixture was refluxed for 5 hours. After refluxing, the reaction mixture was concentrated under reduced pressure and the concentrate was poured into hexane, followed by drying of the precipitates obtained under vacuum to obtain a binder 1.

Workup

  1. temperaturethe mixture was refluxed for 5 hours
  2. temperatureAfter refluxing
  3. concentrationthe reaction mixture was concentrated under reduced pressure
  4. additionthe concentrate was poured into hexane
  5. customby drying of the precipitates
  6. customobtained under vacuum
  7. customto obtain a binder 1

Sources & evidence

ORD record
ord-08da486691844c83b9226dff4e7f3b10
Source dataset
uspto-grants-1991_04
Patent number
US05009981

Reaction notes

Loading…