Methyl Acrylate → 1-(2-Carbmethoxyethyl)-2-undecyl-2-imidazoline

HRID 1086443Notes

Reaction equation

HRID 1086443 reaction equation
[CH2:1]([C:12]1[NH:13][CH2:14][CH2:15][N:16]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[C:17]([O:21][CH3:22])(=[O:20])[CH:18]=[CH2:19]>C(Cl)Cl>[C:17]([CH2:18][CH2:19][N:16]1[CH2:15][CH2:14][N:13]=[C:12]1[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])([O:21][CH3:22])=[O:20]

Participants

4

Reactant 2

HCID 7294Methyl AcrylateHCID 2458582-Undecylimidazoline

Product 1

HCID 151582881-(2-Carbmethoxyethyl)-2-undecyl-2-imidazolineYield 72.4%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2.2 g (9.82 mmoles) of 2-undecyl-2-imidazoline and 1.4 g (16.3 mmoles) of methyl acrylate were dissolved in 50 ml of methylene chloride and the solution was heated to reflux. The reaction was followed by glc. The solution was concentrated and the residue was distilled at 160°-170° C./0.1 mm to give 2.2 g (72.4%) of product.

Workup

  1. temperaturethe solution was heated to reflux
  2. concentrationThe solution was concentrated
  3. distillationthe residue was distilled at 160°-170° C./0.1 mm

Sources & evidence

ORD record
ord-c46d2a1cc86b44dd8ee46f2fbb7ca8c9
Source dataset
uspto-grants-1991_07
Patent number
US05030629

Reaction notes

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