Trifluoroacetic acid → HCID 54090713, compound

HRID 1086693Notes

Reaction equation

HRID 1086693 reaction equation
[F:1][C:2]([F:7])([F:6])[C:3]([OH:5])=[O:4].[CH2:8]=[CH:9][CH:10]=[CH2:11]>C1C=CC=CC=1.C([O-])(=O)C.[Pd+2].C([O-])(=O)C>[F:1][C:2]([F:7])([F:6])[C:3]([O:5][CH:8]=[CH:9][CH2:10][CH2:11][CH2:11][CH2:10][CH:9]=[CH2:8])=[O:4]

Participants

5

Reactant 2

HCID 6422Trifluoroacetic acidHCID 78451,3-Butadiene

Product 1

HCID 54090713HCID 54090713, compound

Reagents, catalysts & solvents 2

HCID 167845palladium(II) acetateCatalystHCID 241BenzeneSolvent

Procedure

1,7-Octadienyl trifluoroacetate was prepared by reacting 1 g of palladium acetate in 20 ml of benzene with 102 g of trifluoroacetic acid and 0.96 M butadiene in a 300 ml autoclave at ambient temperature for 4 days.

Workup

  1. customat ambient temperature
  2. customfor 4 days

Sources & evidence

ORD record
ord-42271215719147288fb6d9661509d6b9
Source dataset
uspto-grants-1991_07
Patent number
US05030792

Reaction notes

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