m-Chloroperbenzoic acid → HCID 22164143, compound

HRID 1087886Notes

Reaction equation

HRID 1087886 reaction equation
[F:1][CH2:2][CH2:3][O:4][C:5]1[CH:12]=[CH:11][CH:10]=[CH:9][C:6]=1C=O.ClC1C=CC=C([C:20]([O:22]O)=[O:21])C=1>C(Cl)Cl>[CH:20]([O:22][C:6]1[CH:9]=[CH:10][CH:11]=[CH:12][C:5]=1[O:4][CH2:3][CH2:2][F:1])=[O:21]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 11400997HCID 11400997, compound

Product 1

HCID 22164143HCID 22164143, compoundYield 62%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

In a manner similar to that disclosed by Godfrey et al., (J. Chem. Soc. Perkin I, 1353-1354 (1974), the reaction of 10.0 grams (0.06 mole) of 2-(2-fluoroethoxy)benzaldehyde with 3-chloroperbenzoic acid (15.5 grams of 80-85% assay, 0.075 mole) in 250 ml of methylene chloride yielded 6.85 grams of 2-(2-fluoroethoxy)phenyl formate as an oil.

Sources & evidence

ORD record
ord-07f8a44267db49759cb85025f6646fe0
Source dataset
uspto-grants-1990_10
Patent number
US04960884

Reaction notes

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