Nitromethane → N-Benzyl-1-(methylsulfanyl)-2-nitroethen-1-amine

HRID 1089593Notes

Reaction equation

HRID 1089593 reaction equation
[CH3:1][S:2][C:3](SC)=[N:4][CH2:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[N+:14]([CH3:17])([O-:16])=[O:15]>>[CH2:5]([NH:4][C:3]([S:2][CH3:1])=[CH:17][N+:14]([O-:16])=[O:15])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Participants

3

Reactant 2

HCID 6375NitromethaneHCID 11790510HCID 11790510, compound

Product 1

HCID 71391850N-Benzyl-1-(methylsulfanyl)-2-nitroethen-1-amine

Procedure

A mixture of nitromethane (4 ml), zeolite, RE 70 Na-Y (500 mg) and benzyl carbonimidodithioic acid dimethyl ester (XI, 500 mg) was refluxed for 110 hr. It was filtered and filtrate concentrated and treated with pet. ether. The solid that separated out was filtered and characterized as compound XII.

Workup

  1. temperaturewas refluxed for 110 hr
  2. filtrationIt was filtered
  3. concentrationfiltrate concentrated
  4. additiontreated with pet. ether
  5. customThe solid that separated out
  6. filtrationwas filtered

Sources & evidence

ORD record
ord-559a363de9d54431b4d93d6e60700340
Source dataset
uspto-grants-1990_10
Patent number
US04967007

Reaction notes

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