Ethyl Acrylate → HCID 14419664, compound

HRID 1090357Notes

Reaction equation

HRID 1090357 reaction equation
[C:1]([O:5][CH2:6][CH3:7])(=[O:4])[CH:2]=[CH2:3].[CH3:8][O:9][CH:10]([O:13][CH3:14])[CH:11]=[O:12]>CO>[CH3:8][O:9][CH:10]([O:13][CH3:14])[CH:11]([OH:12])[C:2]([C:1]([O:5][CH2:6][CH3:7])=[O:4])=[CH2:3]

Participants

4

Reactant 2

HCID 8821Ethyl AcrylateHCID 162650Acetaldehyde, 2,2-dimethoxy-

Product 1

HCID 14419664HCID 14419664, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

118 mmoles ethyl acrylate and 10 g (86.5 mmoles) of 90% by weight dimethoxyethanal in methanol were reacted using the method of example 1 to form 4,4-dimethoxy-2-ethoxycarbonyl-3-hydroxy-1-butene as a liquid which distilled at 108° C. under 0.3 mbar.

Sources & evidence

ORD record
ord-82246b4ffff346a2aeccc9f5b4a05319
Source dataset
uspto-grants-1992_01
Patent number
US05081276

Reaction notes

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