Oxygen → 2-Nitrobenzaldehyde

HRID 1090873Notes

Reaction equation

HRID 1090873 reaction equation
O1CCN(C=[CH:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[N+:15]([O-:17])=[O:16])CC1.[O:18]=O>Cl[Cu].CS(C)=O>[N+:15]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][C:9]=1[CH:8]=[O:18])([O-:17])=[O:16]

Participants

5

Reactant 2

HCID 977OxygenHCID 54256704HCID 54256704, compound

Product 1

HCID 111012-Nitrobenzaldehyde

Reagents, catalysts & solvents 2

HCID 62652Cuprous chlorideCatalystHCID 679Dimethyl SulfoxideSolvent

Procedure

50 mmol of β-morpholino-2-nitrostyrene and 1 g of CuCl were initially introduced into 120 ml of DMSO and aerated at 60° C. for 90 min. using oxygen. After concentrating and customary working-up, 0.41 mol of o-nitrobenzaldehyde was isolated.

Workup

  1. concentrationAfter concentrating

Sources & evidence

ORD record
ord-ef8e2d01f5f5496397b8c0fb5f24c393
Source dataset
uspto-grants-1992_01
Patent number
US05082976

Reaction notes

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