Carbon Dioxide → HCID 19105159, compound

HRID 1091070Notes

Reaction equation

HRID 1091070 reaction equation
[F:1][C:2]([F:17])([F:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13](O)=[O:14].C(Cl)(=O)C([Cl:21])=O.C(=O)=O>C(Cl)Cl.CN(C)C=O>[F:1][C:2]([F:17])([F:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([Cl:21])=[O:14]

Participants

6

Reactant 3

HCID 280Carbon DioxideHCID 65578Oxalyl chlorideHCID 981373812,12,12-trifluorododecanoic Acid

Product 1

HCID 19105159HCID 19105159, compound

Reagents, catalysts & solvents 2

HCID 6228DimethylformamideCatalystHCID 6344DichloromethaneSolvent

Procedure

Dissolve 12,12,12-trifluorododecanoic acid (244 mg, 0.96 mmol) in methylene chloride (5 mL) and add dimethylformamide (3 drops). Add oxalyl chloride (85 μL, 0.96 mmol) and stir until evolution of carbon dioxide is complete to give 12,12,12-trifluorododecanoyl chloride.

Sources & evidence

ORD record
ord-f90294d5ddf54538bd0ba838d055306f
Source dataset
uspto-grants-1992_01
Patent number
US05084461

Reaction notes

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