Sodium hydride → HCID 67920014, compound

HRID 1091202Notes

Reaction equation

HRID 1091202 reaction equation
[H-].[Na+].[C:3]([CH2:6][C:7](=[O:9])[CH3:8])(=[O:5])[CH3:4].[CH3:10][N:11]([CH3:49])[C:12]1[CH:17]=[CH:16][C:15]([C:18]([C:41]2[CH:46]=[CH:45][C:44]([O:47][CH3:48])=[CH:43][CH:42]=2)(O)[CH:19]=[CH:20][CH:21]=[C:22]([C:31]2[CH:36]=[CH:35][C:34]([N:37]([CH3:39])[CH3:38])=[CH:33][CH:32]=2)[C:23]2[CH:28]=[CH:27][C:26]([O:29][CH3:30])=[CH:25][CH:24]=2)=[CH:14][CH:13]=1.Cl([O-])(=O)(=O)=O>CN(C)C=O>[CH3:39][N:37]([CH3:38])[C:34]1[CH:33]=[CH:32][C:31]([C:22]([C:23]2[CH:28]=[CH:27][C:26]([O:29][CH3:30])=[CH:25][CH:24]=2)=[CH:21][CH2:20][CH:19]=[C:18]([C:15]2[CH:16]=[CH:17][C:12]([N:11]([CH3:49])[CH3:10])=[CH:13][CH:14]=2)[C:41]2[CH:46]=[CH:45][C:44]([O:47][CH3:48])=[CH:43][CH:42]=2)=[CH:36][CH:35]=1.[C:3]([CH2:6][C:7](=[O:9])[CH3:8])(=[O:5])[CH3:4]

Participants

5

Reactant 3

HCID 24758Sodium hydrideHCID 31261AcetylacetoneHCID 131717160HCID 131717160, compound

Product 1

HCID 67920014HCID 67920014, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

1.2 g of a 60% sodium hydride was dispersed in 200 ml of well-dried N,N-dimethylformamide (DMF) in a 300-ml. Erlenmeyer flask. To this dispersion, 3.00 g of acetylacetone was slowly added at room temperature and the mixture was stirred for 1 hour. To this mixture, 12.3 g of 1,5-bis-(p-dimethylaminophenyl)-1,5-bis-(p-methoxyphenyl)-2,4-pentadiene-1-ol-perchlorate prepared in Synthesis Example 2-2 was slowly added. This reaction mixture was stirred at room temperature for 1 hour.

Workup

  1. additionwas slowly added
  2. stirringThis reaction mixture was stirred at room temperature for 1 hour

Sources & evidence

ORD record
ord-73a1087befec48b1954e813a6d7c3f38
Source dataset
uspto-grants-1992_01
Patent number
US05084593

Reaction notes

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