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HRID1095188

反应详情

EQUATION

反应方程式

HRID 1095188 的结构方程式

REACTANTS

反应物

4
结构：CC(=O)Cl
HCID6367

Acetyl chloride

C2H3ClO

结构：C[Si](C)(C)Cl
HCID6397

Chlorotrimethylsilane

C3H9ClSi

结构：C[Si](C)(C)[N-][Si](C)(C)C.[Li+]
HCID2733832

Lithium Hexamethyldisilazide

C6H18LiNSi2

结构：O=Cc1cc(F)ccc1OC1CCCC1
HCID57743220

未命名化合物

PRODUCTS

生成物

1
结构：C=C(N=Cc1cc(F)ccc1OC1CCCC1)O[Si](C)(C)C
HCID66640634

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCN(CC)CC
溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

In a manner similar to the method described in Example 112b, 5-fluoro-2-(cyclopentyloxy)-benzaldehyde was treated with LHMDS, acetyl chloride, triethylamine and chloro-trimethyl-silane to give the desired compound, which was directly used for the next step.