Acetate → 3-Aminobiphenyl

HRID 110655Notes

Reaction equation

HRID 110655 reaction equation
[Br:16][c:17]1[cH:18][c:19]([NH2:20])[cH:21][cH:22][cH:23]1.[C:10](=[O:11])([O-:12])[O-:13].[CH3:24][OH:25].[Na+:14].[Na+:15].[O-:27][C:28]([CH3:29])=[O:30].[O-:31][C:32]([CH3:33])=[O:34].[OH:1][B:2]([OH:3])[c:4]1[cH:5][cH:6][cH:7][cH:8][cH:9]1.[Pd+2:26]>>[c:4]1(-[c:17]2[cH:18][c:19]([NH2:20])[cH:21][cH:22][cH:23]2)[cH:5][cH:6][cH:7][cH:8][cH:9]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 887MethanolHCID 923Sodium ion2×HCID 115623-BromoanilineHCID 19660Carbonate IonHCID 66827Phenylboronic AcidHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 167173-Aminobiphenyl

Sources & evidence

ORD record
ord-bb765b207b634c30a74891b977ead518
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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