Methyl Bromide → 1,1-Ethanediol, 1,1-diacetate
Reaction equation
CBr.[C:3]([O:6][CH:7]=[CH2:8])(=[O:5])[CH3:4]>C(O)(=O)C>[C:3]([O:6][CH:7]([O:6][C:3](=[O:5])[CH3:4])[CH3:8])(=[O:5])[CH3:4]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
The procedure of Example 9 was repeated except that 10 g of methyl bromide was used in place of methyl iodide and the reaction was effected for 6 hours. GC analysis showed that 0.212 g of vinyl acetate and 65.8 g of ethylidene diacetate were formed with considerable amount of acetic acid.
Sources & evidence
- ORD record
- ord-0b7fc084fffb4863a4fbf122954b1f1a
- Source dataset
- uspto-grants-1990_12
- Patent number
- US04978778
Reaction notes
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